Solution-based self-assembly synthesis of two-dimensional-ordered mesoporous conducting polymer nanosheets with versatile properties

Facai Wei, Tingting Zhang, Renhao Dong, Yong Wu, Wenda Li, Jianwei Fu, Chengbin Jing, Jiangong Cheng, Xinliang Feng, Shaohua Liu

Published: 2023-07-16 DOI: 10.1038/s41596-023-00845-4

mesoporous conducting polymers

self-assembly synthesis

2D nanosheets

electrochemical energy storage

high-performance electrodes

AI 解读

Extraction of nuclei from archived postmortem tissues for single-nucleus sequencing applications

High-quality and robust protein quantification in large clinical/pharmaceutical cohorts with IonStar proteomics investigation

Longitudinal interrogation of sympathetic neural circuits and hemodynamics in preclinical models

Experimental modulation of physiological force application on leg joint neurons in intactDrosophila melanogaster

Combining surface-accessible Ag and Au colloidal nanomaterials with SERS for in situ analysis of molecule–metal interactions in complex solution environments

Generation of mouse–human chimeric embryos

Labeling and tracking of immune cells in ex vivo human skin

Large-scale preparation of fluorescence multiplex host cell reactivation (FM-HCR) reporters

Mutate-and-chemical-shift-fingerprint (MCSF) to characterize excited states in RNA using NMR spectroscopy

Comprehensive multi-attribute method workflow for biotherapeutic characterization and current good manufacturing practices testing

查看全部

Sections

Figures

References

Introduction
Materials
Procedure 1: synthesis of hybrid nanosheets and example application
Procedure 2: synthesis of mPPy nanosheets and example application
Procedure 3: synthesis of PANi nanosheets and study of their electrical properties
Troubleshooting
Timing
Anticipated results
Acknowledgements

Jia, S. et al. Hierarchical metal-polymer hybrids for enhanced CO2 electroreduction. Angew. Chem. Int. Ed. 60, 10977–10982 (2021).
Shirakawa, H. et al. Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH)x. J. Chem. Soc. Chem. Commun. 16, 578–580 (1977).
Liu, S. et al. Carbonized polyaniline activated peroxymonosulfate (PMS) for phenol degradation: role of PMS adsorption and singlet oxygen generation. Appl. Catal. B 286, 119921 (2021).
Nezakati, T. et al. Conductive polymers: opportunities and challenges in biomedical applications. Chem. Rev. 118, 6766–6843 (2018).
Xu, X. et al. Thermal transport in conductive polymer-based materials. Adv. Funct. Mater. 30, 1904704 (2020).
Luo, H. et al. Nanoarchitectured porous conducting polymers: from controlled synthesis to advanced applications. Adv. Mater. 33, 2007318 (2021).
Qin, J. et al. Hierarchical ordered dual-mesoporous polypyrrole/graphene nanosheets as bi-functional active materials for high-performance planar integrated system of micro-supercapacitor and gas sensor. Adv. Funct. Mater. 30, 1909756 (2020).
Tian, H. et al. General interfacial self-assembly engineering for patterning two-dimensional polymers with cylindrical mesopores on graphene. Angew. Chem. Int. Ed. Engl. 58, 10173–10178 (2019).
Yin, F. et al. Synthesis of mesoporous hollow polypyrrole spheres and the utilization as supports of high loading of Pt nanoparticles. Mater. Lett. 207, 225–229 (2017).
Wang, Q. et al. Mesoporous polyaniline film on ultra-thin graphene sheets for high performance supercapacitors. J. Power Sources 247, 197–203 (2014).
Wu, S. et al. Synthesis of mesoporous silica nanoparticles. Chem. Soc. Rev. 42, 3862–3875 (2013).
Park, S. et al. Hollow mesoporous functional hybrid materials: fascinating platforms for advanced applications. Adv. Funct. Mater. 28, 1703814 (2018).
Ren, Y. et al. Ordered mesoporous metal oxides: synthesis and applications. Chem. Soc. Rev. 41, 4909–4927 (2012).
Malgras, V. et al. Coalescence-driven verticality in mesoporous TiO2 thin films with long-range ordering. J. Am. Chem. Soc. 142, 15815–15822 (2020).
Guo, B. et al. Controlled synthesis of porous carbon nanostructures with tunable closed mesopores via a silica-assisted coassembly strategy. CCS Chem. 3, 1410–1422 (2021).
Dai, F. et al. Bottom-up synthesis of high surface area mesoporous crystalline silicon and evaluation of its hydrogen evolution performance. Nat. Commun. 5, 3605 (2014).
Zhao, T. et al. Interfacial assembly directed unique mesoporous architectures: from symmetric to asymmetric. Acc. Mater. Res. 1, 100–114 (2020).
Li, Q. et al. Ordered bicontinuous mesoporous polymeric semiconductor photocatalyst. ACS Nano 14, 13652–13662 (2020).
Fang, Y. et al. Growth of single-layered two‐dimensional mesoporous polymer/carbon films by self‐assembly of monomicelles at the interfaces of various substrates. Angew. Chem. Int. Ed. 127, 8545–8549 (2015).
Novoselov, K. S. et al. Room-temperature quantum Hall effect in graphene. Science 315, 1379–1379 (2007).
Li, W. et al. Phase transitions in 2D materials. Nat. Rev. Mater. 6, 829–846 (2021).
Schulman, D. et al. Contact engineering for 2D materials and devices. Chem. Soc. Rev. 47, 3037–3058 (2018).
Boota, M. et al. Pseudocapacitive electrodes produced by oxidant‐free polymerization of pyrrole between the layers of 2D titanium carbide (MXene). Adv. Mater. 28, 1517–1522 (2016).
Wang, X. et al. Ultrathin polypyrrole nanosheets via space-confined synthesis for efficient photothermal therapy in the second near-infrared window. Nano Lett. 18, 2217–2225 (2018).
Wang, J. et al. Electrochemical energy storage performance of 2D nanoarchitectured hybrid materials. Nat. Commun. 12, 3563 (2021).
Tian, H. et al. Growth of 2D mesoporous polyaniline with controlled pore structures on ultrathin MoS2 nanosheets by block copolymer self-assembly in solution. ACS Appl. Mater. Interfaces 9, 43975–43982 (2017).
Liu, Z. et al. High power in‐plane micro‐supercapacitors based on mesoporous polyaniline patterned graphene. Small 13, 1603388 (2017).
Zhang, Y. et al. Charge‐enriched strategy based on MXene-based polypyrrole layers toward dendrite-free zinc metal anodes. Adv. Energy Mater. 12, 2103979 (2022).
Li, X. et al. Synthesis of graphene films on copper foils by chemical vapor deposition. Adv. Mater. 28, 6247–6252 (2016).
Yang, H. et al. Free-standing and oriented mesoporous silica films grown at the air-water interface. Nature 381, 589–592 (1996).
Wei, F. et al. Soft template-mediated coupling construction of sandwiched mesoporous PPy/Ag nanoplates for rapid and selective NH3 sensing. J. Mater. Chem. A 9, 8308–8316 (2021).
Qin, J. et al. Achieving stable Na metal cycling via polydopamine/multilayer graphene coating of a polypropylene separator. Nat. Commun. 12, 5786 (2021).
Shi, H. et al. A two-dimensional mesoporous polypyrrole-graphene oxide heterostructure as a dual-functional ion redistributor for dendrite-free lithium metal anodes. Angew. Chem. Int. Ed. 132, 12245–12251 (2020).
Li, W. et al. Ordered mesoporous materials based on interfacial assembly and engineering. Adv. Mater. 25, 5129–5152 (2013).
Liu, S. et al. Patterning two-dimensional free-standing surfaces with mesoporous conducting polymers. Nat. Commun. 6, 8817 (2015).
Liu, S. et al. Dual‐template synthesis of 2D mesoporous polypyrrole nanosheets with controlled pore size. Adv. Mater. 28, 8365–8370 (2016).
Liu, S. et al. Two‐dimensional mesoscale-ordered conducting polymers. Angew. Chem. Int. Ed. 128, 12704–12709 (2016).
Wen, Y. et al. Constructing polymers towards ultrathin nanosheets with dual mesopores and intrinsic photoactivity. Chem. Commun. 56, 3191–3194 (2020).
Ai, Y. et al. General construction of 2D ordered mesoporous iron-based metal-organic nanomeshes. Small 16, 2002701 (2020).
Wei, F. et al. Controllably engineering mesoporous surface and dimensionality of SnO2 toward high‐performance CO2 electroreduction. Adv. Funct. Mater. 30, 2002092 (2020).
Wei, D. et al. A nanostructured electrochromic supercapacitor. Nano Lett. 12, 1857–1862 (2012).
Meng, Q. et al. Research progress on conducting polymer based supercapacitor electrode materials. Nano Energy 36, 268–285 (2017).
Hua, M. et al. Tough-hydrogel reinforced low-tortuosity conductive networks for stretchable and high-performance supercapacitors. Adv. Mater. 33, 2100983 (2021).
Zhao, Z. et al. Designing flexible, smart and self-sustainable supercapacitors for portable/wearable electronics: from conductive polymers. Chem. Soc. Rev. 50, 12702–12743 (2021).
Kurra, N. et al. Conducting polymer micro-supercapacitors for flexible energy storage and Ac line-filtering. Nano Energy 13, 500–508 (2015).
Goikolea, E. et al. Na‐ion batteries—approaching old and new challenges. Adv. Energy Mater. 10, 2002055 (2020).
Xiang, X. et al. Recent advances and prospects of cathode materials for sodium‐ion batteries. Adv. Mater. 27, 5343–5364 (2015).
Deng, Y. et al. Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly (ethylene oxide)-b-polystyrene. J. Am. Chem. Soc. 129, 1690–1697 (2007).
Parviz, D. et al. Dispersions of non-covalently functionalized graphene with minimal stabilizer. ACS Nano 6, 8857–8867 (2012).
Shimizu, T. et al. Supramolecular nanotube architectures based on amphiphilic molecules. Chem. Rev. 105, 1401–1444 (2005).
Liu, S. et al. Soft-template construction of 3D macroporous polypyrrole scaffolds. Small 13, 1604099 (2017).
Parvez, K. et al. Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. J. Am. Chem. Soc. 136, 6083–6091 (2014).

Solution-based self-assembly synthesis of two-dimensional-ordered mesoporous conducting polymer nanosheets with versatile properties

Supplementary information

推荐阅读